丁香园AV

Abstract

Atomistic understanding of charge transfer processes at redox active transition metal oxide surfaces are central to the development of large鈥恠cale energy storage and conversion technologies. Here, we describe our efforts in bridging the conceptual disconnect between molecular and solid鈥恠tate cation鈥恈oupled electron transfer processes through investigations of charge transfer in a family of polyoxovanadate鈥恆lkoxide clusters. This talk will highlight recent results and unpublished work from our group, interrogating the interactions of alkali ions and protons with the surface of the redox active vanadium oxide assemblies. These studies provide insight into how the manipulation of the surface structure of the cluster can influence mechanisms of charge transfer relevant to energy storage and small molecule activation.